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Graphene Fluoride: A Stable Stoichiometric Graphene Derivative and its Chemical Conversion to Graphene

机译：氟化石墨烯：稳定的化学计量的石墨烯衍生物及其化学转化成石墨烯

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Stoichoimetric graphene fluoride monolayers are obtained in a single step by the liquid-phase exfoliation of graphite fluoride with sulfolane. Comparative quantum-mechanical calculations reveal that graphene fluoride is the most thermodynamically stable of five studied hypothetical graphene derivatives; graphane, graphene fluoride, bromide, chloride, and iodide. The graphene fluoride is transformed into graphene via graphene iodide, a spontaneously decomposing intermediate. The calculated bandgaps of graphene halides vary from zero for graphene bromide to 3.1 eV for graphene fluoride. It is possible to design the electronic properties of such two-dimensional crystals.

机译：化学计量的氟化石墨烯单层是通过将氟化石墨与环丁砜液相剥离而在一个步骤中获得的。比较的量子力学计算表明，氟化石墨烯是五个研究的假设的石墨烯衍生物中最热力学稳定的。石墨烯，氟化石墨烯，溴化物，氯化物和碘化物。氟化石墨烯通过碘化石墨烯（自发分解的中间体）转变为石墨烯。卤化石墨烯的计算带隙从溴化石墨烯的零到氟化石墨烯的3.1 eV不等。可以设计这种二维晶体的电子性质。

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作者
Zbořil, Radek; Karlický, František; Bourlinos, Athanasios B; Steriotis, Theodore A; Stubos, Athanasios K; Georgakilas, Vasilios; Šafářová, Klára; Jančík, Dalibor; Trapalis, Christos; Otyepka, Michal;
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年度 2010
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1. Graphene fluoride: A stable stoichiometric graphene derivative and its chemical conversion to graphene [J] . Zbo?il R., Karlicky F., Bourlinos A.B., Small . 2010,第24期

机译：氟化石墨烯：稳定的化学计量的石墨烯衍生物及其化学转化成石墨烯
2. Cyanographene and Graphene Acid: The Functional Group of Graphene Derivative Determines the Application in Electrochemical Sensing and Capacitors [J] . Cheong Yi Heng, Nasir Muhammad Zafir Mohamad, Bakandritsos Aristides, ChemElectroChem . 2019,第1期

机译：Cyanographene和石墨烯酸：石墨烯衍生物的官能团决定了电化学传感和电容器中的应用
3. The production of chemically converted graphenes from graphite fluoride [J] . Athanasios B. Bourlinos, Klara Safarova, Karolina Siskova Carbon: An International Journal Sponsored by the American Carbon Society . 2012,第3期

机译：由氟化石墨生产化学转化的石墨烯
4. Surface Charge Research of Graphene Oxide, Chemically Reduced Graphene Oxide and Thermally Exfoliated Graphene Oxide [C] . Ming-jie Li, Chen-ming Liu, Hong-bin Cao, International Conference on Materials Science Technology . 2013

机译：石墨烯氧化物，化学氧化石墨烯和热剥离石墨烯氧化物的表面电荷研究
5. Study of chemical doping of graphene on amorphous silica, electronic properties of the graphene-fluorine super-lattice and interactions of graphene with atomic fluorine [D] . Shen, Ning 2011

机译：石墨烯化学掺杂对无定形二氧化硅的化学掺杂，石墨烯 - 氟超晶格的电子性质及石墨烯与原子氟相互作用的研究
6. Graphene Fluoride: A Stable Stoichiometric Graphene Derivative and its Chemical Conversion to Graphene [O] . Radek Zbořil, František Karlický, Athanasios B Bourlinos, -1

机译：氟化石墨烯：稳定的化学计量的石墨烯衍生物及其化学转化成石墨烯
7. Nonlinear optical response of some Graphene oxide and Graphene fluoride derivatives [O] . Liaros Nikolaos, Orfanos Ioannis, Papadakis Ioannis, 2016

机译：一些石墨烯的非线性光学响应氧化物和石墨烯氟化物衍生物
8. Development and Exploration of Nanoparticle Decorated Carbon Supports (Graphene and Graphene Oxide) for Energy Collection, Storage, and Conversion. [R] . Loh, K. P. 2012

机译：用于能量收集，储存和转换的纳米颗粒装饰碳载体（石墨烯和氧化石墨烯）的开发和探索。

Graphene Fluoride: A Stable Stoichiometric Graphene Derivative and its Chemical Conversion to Graphene

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